Fluoroplastics refer to plastics made of fluororesin. The main varieties include polytetrafluoroethylene, tetrafluoroethylene ethylene copolymer, tetrafluoroethylene hexafluoropropylene copolymer, and trifluoroethylene ethylene copolymer.Because the molecular structure of fluoroplastics contains fluorine atoms, it has many excellent properties, such as excellent electrical insulation, high heat resistance, outstanding oil resistance, solvent resistance and abrasion resistance, good moisture resistance and low temperature resistance. Therefore, fluoroplastics play an important role in industrial sectors such as national defense, electromechanical, metallurgical, and petrochemical industries.This article introduces the determination of total fluorine content in plastics by ion chromatography combustion method.